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As you can see in the picture I have no button for edge fillet blending corner nor I am able to select any point manually. I have tested this on every other part and still the same result as can be seen from the picture.
Specs: Catia V5R20
you will have to right click in the blend corner to choose vertex or edges and then select the point or edge.Licensing may also be an issue but i dont think there is any license issue here.
Hope it helps.